Copper(II) Dinuclear Pyrazine-Based Rack-Type Complexes: Preparation, Structure, and Magnetic Properties
✍ Scribed by Ramírez, Juan; Stadler, Adrian-Mihail; Rogez, Guillaume; Drillon, Marc; Lehn, Jean-Marie
- Book ID
- 120085760
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 998 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The 1:1 reactions of the new bis(terdentate) diamide ligand__N__,__N____'__‐bis(2‐pyridylmethyl)pyrazine‐2,5‐dicarboxamide(H~2~L^1^) and its higher homologue __N__,__N____'__‐bis[2‐(2‐pyridyl)ethyl]pyrazine‐2,5‐dicarboxamide (H~2~L^2^) with Cu(BF~4~)~2~·4 H~2~O in the absence of added b
The luminescence spectra and lifetimes (at room temperature and 77 K) and triplet-triplet transient absorption spectrum (at room temperature) of a rack-type complex (4) made of two Ru(II) ions, a bridging ligand (3) containing a bis-(bipyridyl)pyrimidine subunit (2) covalently linked to an anthracen