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Copper(II) complexes of diastereoisomeric dipeptides in aqueous solution. Effect of side-chain groups on the thermodynamic stereoselectivity

✍ Scribed by Bonomo, Raffaele P.; Cali, Rosario; Cucinotta, Vincenzo; Impellizzeri, Giuseppe; Rizzarelli, Enrico

Book ID: 121396262
Publisher: American Chemical Society
Year: 1986
Tongue: English
Weight: 729 KB
Volume: 25
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00230a023

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## Abstract The circular dichroism (CD) spectrum of poly‐L‐lysine and poly‐L‐glutamic acid has been investigated in the presence of a small percent of side‐chain blocking groups. The blocking groups benzyl, methyl, and carbobenzoxy show qualitatively similar effects. Less than five mole percent of