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Copper(II) complex of sulfur-containing peptides. Characterization and similarity of electron spin resonance spectrum to the chromophore in blue copper proteins

✍ Scribed by Sugiura, Yukio; Hirayama, Yoshinobu; Tanaka, Hisashi; Ishizu, Kazuhiko

Book ID: 126022353
Publisher: American Chemical Society
Year: 1975
Tongue: English
Weight: 570 KB
Volume: 97
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00852a043

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Electronic properties of sulfhydryl- and imidazole-containing peptide-cobalt(II) complexes: their relationship to cobalt(II)-substituted “blue” copper proteins

✍ Yukio Sugiura 📂 Article 📅 1978 🏛 Elsevier Science ⚖ 308 KB

The electronic properties of 2:1 sulfhydryl- and imidazole-containing peptide-Co(II) complexes have been investigated and compared with those of Co(II)-substituted "blue" copper proteins. The Co(II) complexes of N-mercaptoacetyl-L-histidine and 3-mercaptopropionyl-L-histidine gave the ligand field p