## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2 C−H Bonds with Anhydrides, Using O2 as Terminal Oxidant
✍ Scribed by Wang, Wenhui; Luo, Fang; Zhang, Shouhui; Cheng, Jiang
- Book ID
- 115491896
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 775 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0022-3263
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A chelation-assisted palladium-catalyzed acyloxylation of the sp 3 C-H bond of benzyl by carboxylic acid is described, which employs PhI(OAc) 2 as a stoichiometric oxidant. The procedure tolerates a series of functional groups, such as methoxyl, chloro, bromo, iodo, vinyl, formyl, phenolic hydroxyl,
## Abstract Substrates (I) and (VI) react with chelation assistance of the quinoline N‐atom at the 8‐alkyl side chain to give monoacetoxylation products.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.