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Copper(II) Catalysis of Water Oxidation

โœ Scribed by Chen, Zuofeng; Meyer, Thomas J.


Book ID
118751802
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
476 KB
Volume
125
Category
Article
ISSN
0044-8249

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The effects of oxidant, pH and ligands on iron- and copper-catalyzed ascorbate oxidation have been examined. The formation of the catalyst-substrate complex is affected by pH, whereas oxidant affects its breakdown. With copper-ion catalysis, ligands inhibit competitively. With iron catalysis, on the