Copper(II) and nickel(II) complexes of 2-formylpyridine 3-piperidinyl-, 3-hexamethyleneiminyl- and 3-azabicyclo[3.2.2]nonylthiosemicarbazones
β Scribed by Douglas X. West; Christopher E. Ooms; Jill S. Saleda; H. Gebremedhin; Anthony E. Liberta
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 594 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0340-4285
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Cobalt(III) complexes of 2-acetylpyridine 3-pyrrolidinyl-, 3-piperidinyl-, 3-hexamethylcneiminyl-and 3-azabicyclo- ]BF 4 and I-Co(bcn)2]BF 4, respectively; and aceylpyrazine 3-azabicyclo[3.2.2]nonylthiosemicarbazone, [Co(Pzbcn)2]BF4, have been synthesized and their spectral properties measured. The
Reduction of 2-cyanopyridine by sodium in the presence of 3-hexamethyleneiminylthiosemicarbazide produces 2-pyridineformamide 3-hexamethyleneiminylthiosemicarbazone, HAmhexim. Complexes with nickel(II), copper(II) and palladium(II) have been prepared and the following complexes structurally characte