Copper(I)-Promoted Synthesis of Chloromethyl Ketones from Trichloromethyl Carbinols
β Scribed by Ram, Ram N.; Manoj, T. P.
- Book ID
- 120938739
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 94 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A variety of a-chloromethyl, a,a-dichloromethyl, and a,o,u-trichloromethyl ketones were synthesized from aldehyde utilizing cathodic reduction as key reactions. Recently we have found a practically useful electroreductive anionic chain reaction in which aldehyde was efficiently converted into trich
Recently, we have reported that copper(I) methyltrialkylborates readily undergo addition reactions to acrylonitrile, ethyl acrylate, and 1-acyl-Z-vinylcyclopropane.' These reagents also react with relatively active halides such as benzyl,2 allyl, and propargyl halides. 3 Inan attempt to develop the