✦ LIBER ✦
Copper(I) iodide-promoted reaction of some electrophiles with the aluminium enolate generated by the stereoselective conjugate reduction of (7as)-(+)-5,6,7,7a-tetrahydro-7a-methylindan-1,5-dione
✍ Scribed by Daniewski, Andrzej Robert ;Kiegiel, Jarosĺw ;Piotrowska, Emilia ;Warchoł, Tadeusz ;Wojciechowska, Wanda
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 188 KB
- Volume
- 1988
- Category
- Article
- ISSN
- 0947-3440
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✦ Synopsis
Thr cliisohutylaluniinium enolate 2. generated in situ from the rnediotie 1 by conjugatc reduction. can be forced to react with itldrhydcs, ally1 bromides. or acyl chlorides by addition of copper(1) iodide to thc reaction mixture.