Copper(I) complexes with heterocyclic ligands involving the thioamido group
β Scribed by Paule Castan
- Publisher
- Springer
- Year
- 1981
- Tongue
- English
- Weight
- 405 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Bruker SMART CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2000) T min = 0.667, T max = 0.747 15163 measured reflections 5500 independent reflections 4143 reflections with I > 2(I) R int = 0.032 Refinement R[F 2 > 2(F 2 )] = 0.035 wR(F 2 ) = 0.089 S = 1.01 5500
The coordination compounds of copper(I) with nitrogen and sulphur-containing ligands are well known; the coordination number in these complexes usually varies 1'2 from 1 to 3. A few tetra-coordinated complexes have also been reported such as cyano, substituted phosphine and arsine complexes. The lat
## Abstract Diβ and trinuclear complexes of copper(I) bearing bisβ or trisβNβheterocyclic carbene ligands have been prepared and evaluated as catalysts in nitrene transfer reactions from PhI=NTs to unsaturated and saturated substrates (olefin aziridination and CβH bond amidation) and carbene transf