Copper(I) complexes of mono- and bis-ferrocenyl-vinyl 2,2′-bipyridine-ligands: Synthesis and electrochemical properties
✍ Scribed by Dr. Burkhard König; Oliver Möller; Harald Zieg
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 407 KB
- Volume
- 338
- Category
- Article
- ISSN
- 1615-4150
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We have synthesized a new type of tris-2,2'-bipyridine ligand of 7 and 8 do not interact appreciably, as is evident from their with 4,4'-and 6,6'-disubstituted 2,2'-bipyridine (bpy) units. electrochemical and photophysical data. The lifetime of the The terminal 4,4'-disubstituted 2,2'-bipyridine moi
The synthesis of 5%-methyl-2,2%-bipyridine-6-carboxylic acid is described starting from the pivotal 5%-methyl-6-bromo-2,2%-bipyridine building block. Functionalisation of the latest at the 5%-methyl position gives access to the 5%-bromomethyl, 5%-hydroxymethyl and 5%-aminomethyl derivatives. Upon nu