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Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

✍ Scribed by Yusuke Sasaki; Yuko Horita; Dr. Chongmin Zhong; Prof. Dr. Masaya Sawamura; Prof. Dr. Hajime Ito

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
344 KB
Volume
123
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Copper(I)-Catalyzed
ChemInform Abstract: Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates.
✍ Yusuke Sasaki; Yuko Horita; Chongmin Zhong; Masaya Sawamura; Hajime Ito 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

## Abstract The regioselectivity is primarily determined by the substrate structure, whereas for moderately substituted 1,3‐enynes (IV), the catalytic phosphine ligand displays a significant role.