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Copper(I)-catalyzed arylselenylation of aryl bromides and iodides

✍ Scribed by Irina P Beletskaya; Alexander S Sigeev; Alexander S Peregudov; Pavel V Petrovskii


Book ID
104254332
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
202 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new protocol to prepare unsymmetrical diarylselenides using the reaction of aryl bromides and iodides with easily available Bu 3 SnSeAr catalyzed by Cu(I) complexes under rather mild conditions and with a very high yield is described.


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Mild and Efficient Copper-Catalyzed Cyan
✍ Henri-Jean Cristau; Armelle Ouali; Jean-Francis Spindler; Marc Taillefer 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 2 views

## Abstract An efficient copper‐catalyzed cyanation of aryl iodides and bromides is reported. Our system combines catalytic amounts of both copper salts and chelating ligands. The latter, which have potential nitrogen‐ and/or oxygen‐binding sites, have never previously been used in this type of rea