Copper(I)-catalyzed arylselenylation of aryl bromides and iodides
✍ Scribed by Irina P Beletskaya; Alexander S Sigeev; Alexander S Peregudov; Pavel V Petrovskii
- Book ID
- 104254332
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 202 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A new protocol to prepare unsymmetrical diarylselenides using the reaction of aryl bromides and iodides with easily available Bu 3 SnSeAr catalyzed by Cu(I) complexes under rather mild conditions and with a very high yield is described.
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## Abstract An efficient copper‐catalyzed cyanation of aryl iodides and bromides is reported. Our system combines catalytic amounts of both copper salts and chelating ligands. The latter, which have potential nitrogen‐ and/or oxygen‐binding sites, have never previously been used in this type of rea