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Copper(I) and Copper(II) Complexes Possessing Cross-Linked Imidazole-Phenol Ligands: Structures and Dioxygen Reactivity

✍ Scribed by Kamaraj, Kaliappan; Kim, Eunsuk; Galliker, Benedikt; Zakharov, Lev N.; Rheingold, Arnold L.; Zuberbühler, Andreas D.; Karlin, Kenneth D.

Book ID: 115485320
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 89 KB
Volume: 125
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja034263f

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## Abstract Copper(I) bromide complexes (2a and 2b) of NHC–phenolimine ligand precursors {3‐[(1__R__,2__R__)‐2‐{[1‐(3,5‐di‐__tert__‐butyl‐2‐hydroxyphenyl)meth‐(__E__)‐ylidene]amino}cyclohexyl]‐1‐isopropyl‐4‐phenyl‐3__H__‐imidazol‐1‐ium bromide (1a) and 3‐[(1__R__,2__R__)‐2‐{[1‐(2‐hydroxyphenyl)meth