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Copper(0)-mediated radical copolymerization of vinyl acetate and acrylonitrile in DMSO at ambient temperature

✍ Scribed by Huali Yu; Yang Wu; Jinlong Gao; Wenxiang Wang; Zhengbiao Zhang; Xiulin Zhu

Book ID: 115561132
Publisher: John Wiley and Sons
Year: 2012
Tongue: English
Weight: 783 KB
Volume: 50
Category: Article
ISSN: 0887-624X
DOI: 10.1002/pola.26334

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## Abstract **Summary:** Poly(vinyl acetate) macroinitiators end‐capped by a Co(acac)~2~ complex (PVAc–Co(acac)~2~), prepared in bulk by cobalt‐mediated radical polymerization (CMRP), are used for the controlled radical polymerization of vinyl acetate in miniemulsion to give high‐molecular‐weight p