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Copper Salt Catalyzed Addition of Arylboronic Acids to Azodicarboxylates

โœ Scribed by Uemura, Takeshi; Chatani, Naoto


Book ID
118154943
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
89 KB
Volume
70
Category
Article
ISSN
0022-3263

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Nickel salt-catalyzed addition reaction
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Arylation reaction of aromatic aldehydes with arylboronic acids proceeded smoothly in the presence of a base and catalytic amount of a nickel salt, Ni(ClO 4 ) 2 ร6H 2 O, in toluene/IPA = 5:1 or IPA to afford corresponding diarylmethanols in good to excellent yields.