Copper-Catalyzed Reaction of Alkyl Halides with Cyclopentadienylmagnesium Reagent
β Scribed by Sai, Masahiro; Someya, Hidenori; Yorimitsu, Hideki; Oshima, Koichiro
- Book ID
- 125893512
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 126 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
SmI\_JHMPA converts alkyl iodides and bromides to alkyl samarium reagents which can be crosscoupled with primary alkyl icdides and bromides and secondary iodides in the presence of Cu(I) halides or L&CuCl, at room temperature. The alkylation of primary iodides gives good yields of cross-coupling pro
Nickel-and palladium-catalyzed cross-coupling reactions of organic halides with organometallic reagents is one of the most versatile carbonΒ±carbon bond-forming reactions in organic synthesis. [1] In most cases, aryl and vinyl halides are employed as organic halides, yielding sp 2 Β±sp, sp 2 Β±sp 2 , a