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Copper-Catalyzed Direct Amination of Nitrobenzenes with O -Alkylhydroxylamines

โœ Scribed by Seko, Shinzo; Kawamura, Norio

Book ID
120300106
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
92 KB
Volume
61
Category
Article
ISSN
0022-3263

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A convenient copper-catalyzed direct ami
A convenient copper-catalyzed direct amination of nitroarenes with O-alkylhydroxylamines
โœ Seko, Shinzo; Miyake, Kunihito; Kawamura, Norio ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Royal Society of Chemistry โš– 221 KB

O-Alkylhydroxylamines, particularly O-methylhydroxylamine, aminate nitroarenes in the presence of a strong base and a copper catalyst to give aminonitroarenes in good yields. ortho-or para-Amination with respect to the nitro group takes place, and in some cases the ortho-aminated product is preferen