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Copper-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Aryl Iodides and Bromides

✍ Scribed by Rui Shang; Yao Fu; Yan Wang; Qing Xu; Hai-Zhu Yu; Lei Liu

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
411 KB
Volume
121
Category
Article
ISSN
0044-8249

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✍ Thomas Knauber; Fatih Arikan; Prof.β€…Dr. Gerd-Volker RΓΆschenthaler; Prof.β€…Dr. Luk πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 322 KB

## Abstract Potassium (trifluoromethyl)trimethoxyborate is introduced as a new source of CF~3~ nucleophiles in copper‐catalyzed trifluoromethylation reactions. The crystalline salt is stable on storage, easy to handle, and can be obtained in near‐quantitative yields simply by mixing B(OMe)~3~, CF~3