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Copper-catalyzed Csp3–O cross-coupling of unactivated alkyl halides with organic peroxides

✍ Scribed by Chen, Huan-Huan; Wang, Guang-Zu; Han, Jin; Xu, Meng-Yu; Zhao, Yong-Qiang; Xu, Hua-Jian


Book ID
121454481
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
460 KB
Volume
70
Category
Article
ISSN
0040-4020

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Copper-catalyzed cross-coupling of alkyl
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SmI\_JHMPA converts alkyl iodides and bromides to alkyl samarium reagents which can be crosscoupled with primary alkyl icdides and bromides and secondary iodides in the presence of Cu(I) halides or L&CuCl, at room temperature. The alkylation of primary iodides gives good yields of cross-coupling pro