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Copper-Catalyzed Coupling of Aryl Iodides with Aliphatic Alcohols

✍ Scribed by Wolter, Martina; Nordmann, Gero; Job, Gabriel E.; Buchwald, Stephen L.

Book ID
111696873
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
121 KB
Volume
4
Category
Article
ISSN
1523-7060

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An efficient intermolecular BINAM–copper
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A wide range of alkyl aryl ethers are synthesized from the corresponding aryl iodides and aliphatic alcohols through Ullmann-type intermolecular coupling reactions in the presence of a catalytic amount of easily available BINAM-CuI complex. Less reactive aryl bromides have also been shown to react w