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Copper-Catalyzed CH Oxidation/Cross-Coupling of α-Amino Carbonyl Compounds

✍ Scribed by Ji-Cheng Wu; Ren-Jie Song; Zhi-Qiang Wang; Xiao-Cheng Huang; Ye-Xiang Xie; Prof. Dr. Jin-Heng Li

Book ID
111653858
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
480 KB
Volume
51
Category
Article
ISSN
0044-8249

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The copper-catalyzed carbonylative coupling of (El-a-selanylvinylzirconiuma with alkynylicdonium tmylates at r. t. in THF in the presence of 3 mol% CuI, and atmospheric premre of carbon monoxide for 15 min. afforded in fair to good yields the -axpled ketone products.