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Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

✍ Scribed by Keishi Takatsu; Dr. Ryo Shintani; Prof. Dr. Tamio Hayashi

Book ID
101543761
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
315 KB
Volume
123
Category
Article
ISSN
0044-8249

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## Abstract Activation of the SiB inter‐element bond with copper(I) alkoxides produces copper‐based silicon nucleophiles that react readily with aldehydes to yield α‐silyl alcohols (that is, α‐hydroxysilanes) after hydrolysis. Two independent protocols were developed, one employing a well‐defined