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Copper-catalysed oxidation of catechols by dioxygen

✍ Scribed by Gábor Speier


Publisher
Elsevier Science
Year
1986
Weight
562 KB
Volume
37
Category
Article
ISSN
0304-5102

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Copper-catalysed allylic oxidation of Δ5
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A5-7-Oxosteroids are efficiently prepared from A5-steroids with t-BuOOH and a copper catalyst, either Cu(II) and Cu (I) salts or Cu metal; selectivity in the presence of a secondary alcohol is observed.