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Copper ATRP Catalysts with Quadridentate Amine Ligands: The Effects of Steric and Electronic Tuning on the Polymerization of Methyl Methacrylate

โœ Scribed by Johnson, Robert M.; Ng, Christina; Samson, Claire C. M.; Fraser, Cassandra L.


Book ID
118063859
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
227 KB
Volume
33
Category
Article
ISSN
0024-9297

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## Abstract Two new copper(I) complexes, [Cu(bdmpm)~2~](PF~6~) (1) [bis(3,5โ€dimethylโ€1__H__โ€pyrazolโ€1โ€yl)methane (bdmpm)] and [Cu(__ยต__โ€bdmpp)(MeCN)]~2~(PF~6~)~2~ (2) [2,6โ€bis(3,5โ€dimethylโ€1__H__โ€pyrazolโ€1โ€yl)pyridine (bdmpp)], were prepared by reactions of [Cu(MeCN)~4~](PF~6~) with bdmpm or bdmpp