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Copper and Manganese: Two Concordant Partners in the Catalytic Oxidation of p-Cresol to p-Hydroxybenzaldehyde.

โœ Scribed by Feng Wang; Guan-yu Yang; Wei Zhang; Wen-hai Wu; Jie Xu


Publisher
John Wiley and Sons
Year
2003
Weight
89 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Aldehydes Q 0320

Copper and Manganese: Two Concordant Partners in the Catalytic Oxidation of p-Cresol to p-Hydroxybenzaldehyde. -The heterogeneously catalyzed oxidation of p-cresol (I) to p-hydroxybenzaldehyde (II) is carried out over copper and manganese single and bimetallic catalysts. Single component catalysts reveal lower activity and selectivity than bimetallic catalysts. Compared to organometallic catalysts and zeolites, the copper and manganese bimetallic catalyst is less demanding, economical in preparation, and suitable for large-scale production. -(


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Catalytic properties of dinuclear copper
โœ B. Srinivas; P. S. Prakash; P. S. Zacharias ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Springer ๐ŸŒ English โš– 323 KB

Dinuclear copper(II) complexes of differing magnetic and redox properties derived from various dinucleating ligands were investigated for their catalytic activity in the oxidation of 3,5-di-t-butylcatechol (3,5-DTBC) and ascorbic acid by oxygen. Poor activity was exhibited by di-#-hydroxocopper(II)