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Copper and Bismuth Complexes Containing Dipyridyl gem -Diolato Ligands: Bi III2 [(2-Py) 2 CO(OH)] 2 (O 2 CCF 3 ) 4 (THF) 2 , Cu II [(2-Py) 2 CO(OH)] 2 (HO 2 CCH 3 ) 2 , and Cu II4 [(2-Py) 2 CO(OH)] 2 (O 2 CCH 3 ) 6 (H 2 O) 2 , a Ferromagnetically Coupled Tetranuclear Copper(II) Chain

✍ Scribed by Breeze, Steven R.; Wang, Suning; Greedan, John E.; Raju, N. P.


Book ID
127015268
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
209 KB
Volume
35
Category
Article
ISSN
0020-1669

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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê