## Abstract The polymerization of 1‐(1‐cyclopentenyl)vinyl acetate (**1**) and (3‐methyl‐1,3‐butadien‐2‐yl) acetate (**7**) under radical conditions, leading to 1,4‐polymers, and the copolymerization with vinyl monomers were studied. The reactivity ratios are compared with those previously describe
Copolymérisation du dicyanure de propène-1 ylidène-1 avec l'acétate de vinyle et des styrènes substitutés. Calcul des taux de réactivité et étude de l'effet pénultième
✍ Scribed by Monthéard, Jean-Pierre ;Boinon, Bernard ;Raihane, Mustapha ;Pham, Quang-Tho
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1992
- Weight
- 390 KB
- Volume
- 193
- Category
- Article
- ISSN
- 0025-116X
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✦ Synopsis
Abstract
1‐Propen‐1‐ylidene dicyanide was copolymerized in bulk with vinyl acetate and five substituted styrenes. The reactivity ratios of these copolymerizations were calculated by the Fineman‐Ross or the Kelen‐T¨︁udős method. The penultimate model describes satisfactorily the deviation from the terminal model in the copolymerization reactions between 1‐propene‐1‐ylidene dicyanide and the substituted styrenes.
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