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Copolymères du chlorure de vinylidène avec l'acrylonitrile, le chlorure de vinyle et le méthacrylate de méthyle, 2. Fusion — utilisation d'un modèle de simulation

✍ Scribed by Dumont, Bernard ;Berticat, Philippe ;Guillot, Jean

Publisher
Wiley (John Wiley & Sons)
Year
1981
Weight
363 KB
Volume
182
Category
Article
ISSN
0025-116X

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✦ Synopsis

Abstract

The melting point depression in vinylidene chloride copolymers, when introducing an increasing number of units B = vinyl chloride, acrylonitrile or methyl methacrylate is studied in this paper. A Monte‐Carlo simulation model of chains growing and crystallization is applied and allows to know the proportion X~c~ of defects in the crystalline phase. An equation given by Sanchez is then applied, and the excess energy ε of the defect created by the incorporation of a B unit in the crystalline vinylidene chloride lattice is calculated.

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