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Copolymers of N-vinyl-2-pyrrolidone and 2-(dimethylamino)ethyl methacrylate, 1. Synthesis, characterization, quaternization

✍ Scribed by Karine Deboudt; Michèle Delporte; Claude Loucheux

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
468 KB
Volume
196
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

2‐(Dimethylamino)ethyl methacrylate (DMAEM) — N‐vinyl‐2‐pyrrolidone (VP) copolymers were synthesized and characterized. The copolymerization parameters were determined: r~VP~ = 0,61, r~DMAEM~ = 11,41. The tacticity of DMAEM sequences and the distribution of monomer units were estimated. Then, the experimental conditions for the quaternization of the copolymers with alkyl bromides were defined. The modified copolymers were characterized and the mechanism of the quaternization reaction was studied via potentiometry.

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