Copolymers of L-proline and sarcosine: Synthesis and physical-chemical studies
✍ Scribed by G. D. Fasman; E. R. Blout
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1963
- Tongue
- English
- Weight
- 522 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0006-3525
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## Abstract By means of carbon‐13 nmr (at 25 MHz) the __trans/cis__ conformer ratio in glycyl‐L‐proline has been measured in aqueous (D~2~O) solution over the temperature range 33–96°C. It is found that Δ__H__^0^ = −4.2 kJ/mole and Δ__S__^0^ = −9.7 J/mole/K. Measurements of the __T__~1~ values for
## Abstract Amino acid‐based block copolymers containing poly(A‐Pro‐OMe) have been synthesized by RAFT polymerization using the dithioester‐terminated poly(DMA) as a macro‐CTA. An amphiphilic block copolymer composed of polystyrene as a hydrophobic segment and poly(A‐Pro‐OMe) as a hydrophilic segme