## Abstract This contribution presents a kind of novel and neutral network films based on EDOT formed by in situ electrocopolymerization (ECP). The ECP films which are neutral and colorless exhibit the conductivity of 0.2–0.5 S · cm^−1^, __W__~F~ of 4.79–5.20 eV, and RMS roughness of 3.51–5.26 nm.
Copolymers of 3,4-Ethylenedioxythiophene and 3-Methylthiophene: Properties, Applications and Morphologies
✍ Scribed by Cintia Ocampo; Elaine Armelin; Francesc Estrany; Luis J. del Valle; Ramón Oliver; Francesc Sepulcre; Carlos Alemán
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 450 KB
- Volume
- 292
- Category
- Article
- ISSN
- 1438-7492
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✦ Synopsis
Abstract
Copolymers of 3,4‐ethylenedioxythiophene and 3‐methylthiophene have been prepared by recurrent potential pulses using monomer mixtures with various concentration ratios, their properties being compared with those of the corresponding homopolymers. In addition, different technological applications have been tested for the generated copolymers. Results indicate that the properties of the copolymers are closer to those of poly(3,4‐ethylenedioxythiophene) than to those poly(3‐methylthiophene). Furthermore, the ability of the copolymers to store charge and to interact with plasmid DNA suggest that they are very promising materials.
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## Abstract Electrocopolymerization of 3,4‐ethylenedioxythiophene (EDOT) and 5‐methylindole (5MeIn) was successfully carried out in acetonitrile containing lithium perchlorate as supporting electrolyte although the oxidation potentials of 5MeIn and EDOT were quite different. The influence of feed r
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