๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Copolymerizations involving methyl methacrylate, methyl acrylate, stilbene and p.fluorostilbene

โœ Scribed by C.A. Barson; J.C. Bevington

Book ID
103073593
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
154 KB
Volume
23
Category
Article
ISSN
0014-3057

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โœฆ Synopsis

Homopolymerizations and copolymerizations of methyl methacrylate (MMA) and methyl acrylate (MA) have been performed in the presence of either stilbene or p.fluorostilbene, labelled with carbon-14, it has been shown that at 60ยฐC the polyMA radical is much more reactive than the polyMMA radical towards stilbene, the velocity constants for the reactions differing by a factor of about 300; similar results are found for p.fluorostilbene. The differences between the reactivities of the radicals are associated with steric effects arising from the presence of a methyl group at the alpha position in ~tMA.

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