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Copolymerization without initiator of aziridine with succinic anhydride

✍ Scribed by S.A. Pooley; G.S. Canessa; B.L. Rivas

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 229 KB
Volume: 29
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(93)90154-8

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✦ Synopsis

AImraet--The copolymerization of aziridine (Az) as nucleophilic monomer and succinic anhydride as electrophilic monomer without initiator in solution under different mol ratio was investigated. Copolymers were characterized by elemental analyses, i.r. and ~H-NMR spectroscopy. For all feed mole ratio of comonomer, Az is incorporated preferentially in the copolymer. For the soluble copolymers it is possible by ~H-NMR spectroscopy to determine the Az-homodyad concentration. The copolymerization reaction occurs by an intermediate "genetic zwitterion".

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