Copolymerization of α-olefins with ω-halo-α-olefins by use of Ziegler catalysts
✍ Scribed by Bacskai, R.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1965
- Tongue
- English
- Weight
- 998 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0449-2951
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📜 SIMILAR VOLUMES
Results are presented of a n investigation on the polymerizability of functional olefins, such as allylisopropylidene glycerol (AIPG) and undecenylisopropylidene glycerol (UIPG), in the presence of conventional and modified Ziegler-Natta catalysts based on TiC14 or MgC12supported titanium and triiso
## Abstract Ethylene was polymerized at 15,000–25,000 psi at 130–220°C. with free‐radical initiators in the presence of 0–10% of C^14^‐labeled propylene, butene‐1, and octene‐1. Polymer composition was determined by scintillation counting. Molecular weight measurements and polymer unsaturation as d
## Abstract The polymerization of 3‐methylbutene‐1 by TiCl~3~–Al(C~2~H~5~)~3~ catalysts in dilute solution above 80°C. yields a polymer which is contaminated with polyethylene. By using tagged aluminum alkyl, this polyethylene was shown to arise almost wholly by displacement of ethylene from the al