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Copolymerization of ferrocenylacetylene with phenylacetylene

โœ Scribed by B.F. Sokolov; T.P. Vishnyakova; A.S. Kislenko


Book ID
118360298
Publisher
Elsevier Science
Year
1973
Weight
322 KB
Volume
15
Category
Article
ISSN
0032-3950

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Carbon monoxide was copolymerized with phenylacetylene (PA) using initiation by a palladium complex [Pd '(CH ,CN),] (BF,), under various conditions. Good yields were obtained at 90ยฐC in methanol. Elementary analysis, infrared and NMR spectroscopy showed that the copolymers contained ketone and olefi

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## Abstract Copolymerizations of diethyl 7โ€oxabicyclo[2.2.1]heptaโ€2,5โ€dieneโ€2,3โ€dicarboxylate (DOHDD) with phenylacetylene (PA) or __p__โ€methoxyphenylacetylene (MeOPA) were successfully performed in chloroform using PdBr~2~ as catalyst. The products of reactivity ratios __r__~1~ ยท __r__~2~ for poly