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Copolymerization of ethylene and styrene with monocyclopentadienyltitanium trichloride/methylalumoxane catalyst

✍ Scribed by Leone Oliva; Stefano Mazza; Pasquale Longo

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
339 KB
Volume
197
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

A series of ethylene‐styrene copolymerizations was carried out in the presence of cyclopentadienyltitanium trichloride and methylalumoxane at 20Β°C and at different comonomer feed compositions. By sequential extraction a copolymeric material with a styrene units content up to 36 mol‐% can be separated from the homopolymeric products. Some considerations about the relative reactivity of the comonomers and the regioregularity of the styrene insertion are made on the basis of the ^13^C NMR spectra.

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