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Copolymerization of ethylene and propylene catalyzed by magnesium chloride supported vanadium/titanium bimetallic Ziegler-Natta catalysts

✍ Scribed by Tao Jiang; Hong-xia Chen; Chen-gang Cao; Guo-liang Mao; Wei Du; Deng-fei Wang

Publisher
Institute of Chemistry Chinese Academy of Sciences
Year
2011
Tongue
English
Weight
355 KB
Volume
29
Category
Article
ISSN
0256-7679

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Ziegler-Natta catalysts for ethylene and
Ziegler-Natta catalysts for ethylene and propylene polymerizations supported on the products of thermal desolvation of the adducts of magnesium chloride with methyl and ethyl alcohols
✍ D.N. Taveira Magalhães; O. Do Coutto Filho; F.M.B. Coutinho 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 306 KB

MgCl 2 adducts with alcohols and ethers can be converted to more active supports through the elimination of the alcohol molecules from the adducts by thermal desolvation. Catalysts supported on the products of thermal desolvation of the MgCI: adducts with methyl and ethyl alcohols have been prepared

Copolymerization of ethylene and 1-dodec
Copolymerization of ethylene and 1-dodecene catalyzed by novel low-Ti-loading Ziegler–Natta catalysts and their microstructures
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## Abstract Ethylene–1‐dodecene copolymers were synthesized with novel low‐Ti‐loading (0.8 wt %) Ziegler–Natta catalysts prepared by a one‐pot balling method. ^13^C‐NMR was applied for the quantitative determination of the composites and microstructures of the resultant ethylene–1‐dodecene copolyme