𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Copolymerization of divinyl monomers with maleic and fumaric acid derivatives

✍ Scribed by L. Ya. Tsarik; O. N. Novikov; V. V. Magdinets

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
159 KB
Volume
36
Category
Article
ISSN
0887-624X

No coin nor oath required. For personal study only.

✦ Synopsis

The process of formation of reticular copolymer molecular structures produced in free radical copolymerization of divinyl monomers (divinyl ethers of diethylene glycol and hydroquinone, divinyl sulfide, p-divinylbenzene, etc.) with maleic and fumaric acid derivatives is studied. The basic factor that determines the features of molecular and network structures of copolymers is reactivity of the divinyl monomer in copolymerization with monovinyl monomer. The network of copolymers of maleic anhydride with the divinyl ether of hydroquinone is formed out of oligomer microgels. Divinyl sulfide in copolymerization with maleic acid is disposed to cyclocopolymerization; also crosslinking reactions occur. Formation of a network structure of copolymers of divinylbenzene with maleic and fumaric acid derivatives is shown to proceed via an alternating copolymerization mechanism.

📜 SIMILAR VOLUMES

Stereochemical applications of Mass Spec
Stereochemical applications of Mass Spectrometry. Part 5—fragmentation of protonated and methylated maleic and fumaric acid and derivatives
✍ Tu, Ya-Ping; Harrison, Alex G. 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB 👁 2 views

The unimolecular metastable ion and collision-induced dissociation (CID) fragmentation reactions of protonated and methylated monoamides, monomethyl esters and methyl esters of the monoamides of maleic and fumaric acids were studied. In addition, some studies of the fragmentation of protonated and m

Synthesis of Norbornene Derivatives by D
Synthesis of Norbornene Derivatives by Diels-Alder Cycloaddition and Subsequent Copolymerization with Maleic Anhydride
✍ Anthony J. Pasquale; Ann R. Fornof; Timothy E. Long 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract **Summary:** Several norbornene (Nb) derivatives were synthesized by facile Diels‐Alder cycloaddition reactions of cyclopentadiene with __α__‐olefins containing electron‐withdrawing groups such as nitrile (CN), phosphonate, and ester. The Diels‐Alder adducts were subsequently copolymeri