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Copolymerization of CO2 and Epoxides Catalyzed by Metal Salen Complexes

โœ Scribed by Donald J. Darensbourg; Ryan M. Mackiewicz; Andrea L. Phelps; Damon R. Billodeaux


Book ID
101966090
Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Alkene aziridination and epoxidation cat
โœ Kenneth J. O'Connor; Shiow-Jyi Wey; Cynthia J. Burrows ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 285 KB

New chiral metal salen complexes substituted in the 3 position with bulky silyl groups (TM!?, TBDMS) have been synthesized. Although some of these complexes catalyzed the epoxidation of unfunctionalized olefins in moderate to high ee's, they catalyzed the aziridination of cis-P-methylstyrene without