Copolymerization of 4-methyl-1,3-dioxene-4 with maleic anhydride and terpolymerization with styrene as the third component
✍ Scribed by Kawai, Wasaburo
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1968
- Tongue
- English
- Weight
- 351 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0449-296X
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## Abstract The copolymerization of methylenedioxolanes, such as 4‐methylene‐1,3‐dioxolane (I) and 2,2‐dimethyl‐4‐methylene‐1,3‐dioxolane (II), with maleic anhydride (Manh) gives rise spontaneously to the alternating copolymers by the participation of charge‐transfer (CT) complexes. The formation o
Copolymerizations of 4-methylene-2-styryl-1,3-dioxolane (1) and 4-methylene-%methyl-Z-styryl-1,3-dioxolane (2) with electron-deficient monomers, such as maleic anhydride (MA) and acrylonitrile (AN) were investigated. Only homopolymer of 1 was obtained from the copolymerization of 1 with MA in the pr
## Abstract The free‐radical copolymerization of methyl acrylate with styrene initiated by triphenylstibonium 1,2,3,4‐tetraphenylcyclopentadienylide under nitrogen blanket at (60 ± 0.1)°C in 1,4,dioxane for 2 h has been carried out. The kinetic expression is __R~p~__ ∝ [I]^0.14^ [MA]^0.70^ [Sty]^0.