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Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent

✍ Scribed by Super, Michael; Berluche, Enoch; Costello, Christine; Beckman, Eric


Book ID
120456134
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
272 KB
Volume
30
Category
Article
ISSN
0024-9297

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Supercritical carbon dioxide as solvent
✍ Donald J. Darensbourg; Nicole White Stafford; Takumi Katsurao πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 313 KB

Supercritical carbon dioxide was found to be a suitable substitute for halogenated organic solvents in its copolymerization with propylene oxide. The system was studied utilizing a heterogenous catalyst, zinc glutarate. The polymers were analyzed for selectivity in polycarbonate linkages by 'H NMR s