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Cope Rearrangement of cis-Bicyclo[6.1.O]-nona-2,6-diene and Its 9-Hetero Analogs

โœ Scribed by Dr. Wolfram Grimme; Dipl.-Chem. Klaus Seel


Book ID
111698439
Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
243 KB
Volume
12
Category
Article
ISSN
0044-8249

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๐Ÿ“œ SIMILAR VOLUMES


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The discovery' that bicycle [ 5.1.01 o&a-2, S-diene (3,4-hometropilidene, I) undergoes a rapidly reverisible, degenerate Cope roarrangement has stimulated considerable theoretical interest. The generality of such behavior hae recently been put to test by the Syntheal11 of trtcyclo [ 3.3.2. 04' 6] de

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We wish to report the thermal behavior of the cis-bicyclo[6.2.0]decenes, I-III. 1 The known' thermal rearrangement of bicyclo[3\*2.0]hepta-2,6-diene to I II III cycloheptatriene is here shown to be extended to the bicyclic systems above which also possess the condensed cyclobutene moiety. It is also