Cope Rearrangement of cis-Bicyclo[6.1.O]-nona-2,6-diene and Its 9-Hetero Analogs
โ Scribed by Dr. Wolfram Grimme; Dipl.-Chem. Klaus Seel
- Book ID
- 111698439
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 243 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
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The discovery' that bicycle [ 5.1.01 o&a-2, S-diene (3,4-hometropilidene, I) undergoes a rapidly reverisible, degenerate Cope roarrangement has stimulated considerable theoretical interest. The generality of such behavior hae recently been put to test by the Syntheal11 of trtcyclo [ 3.3.2. 04' 6] de
We wish to report the thermal behavior of the cis-bicyclo[6.2.0]decenes, I-III. 1 The known' thermal rearrangement of bicyclo[3\*2.0]hepta-2,6-diene to I II III cycloheptatriene is here shown to be extended to the bicyclic systems above which also possess the condensed cyclobutene moiety. It is also