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Coordinatively Unsaturated 16-Electron Ruthenium Allenylidene Complexes: Synthetic, Structural, and Catalytic Studies

✍ Scribed by Schanz, Hans-Jörg; Jafarpour, Laleh; Stevens, Edwin D.; Nolan, Steven P.

Book ID: 120181932
Publisher: American Chemical Society
Year: 1999
Tongue: English
Weight: 162 KB
Volume: 18
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om9906316

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## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_