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Coordination of histidine-containing ligand-systems to vanadium(IV) and -(V)

✍ Scribed by S. Jantzen; D. Rehder

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 54 KB
Volume: 59
Category: Article
ISSN: 0162-0134
DOI: 10.1016/0162-0134(95)97686-k

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## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3′]H~3~ and [PS3]H~3~ {[PS3′]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4′ (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3′ or PS3 ligands by a disulf