Coordination of Deprotonated Saccharin in Copper(II) Complexes. Structural Role of the Saccharinate Directed by the Ancillary N-heterocyclic Ligands

Structural Studies of a Copper(II) Compl

Structural Studies of a Copper(II) Complex with Inequivalent 2-Acetylpyridine 3-Piperidylthiosemicarbazonato Ligands and a Nickel(II) Complex with Different Modes of Coordination by the Two Thiosemicarbazonato Moieties of 1-Phenylglyoxal Bis{N(4)-diethylthiosemicarbazone}

✍ Elena Bermejo; Alfonso Castiñeiras; Lily J. Ackerman; Matthew D. Owens; Douglas 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 128 KB 👁 2 views

The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur