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Coordination of a closo-Cluster at Rhodium and Iridium

✍ Scribed by Thiemo Marx; Lars Wesemann; Stefanie Dehnen


Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
132 KB
Volume
627
Category
Article
ISSN
0372-7874

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The reaction of 14e [L Me Rh-(coe)] (1; L Me ArNC(Me)CHC(Me)-NAr, Ar 2,6-Me 2 C 6 H 3 ; coe cis-cyclooctene) with phenyl halides and thiophenes was studied to assess the competition between s coordination, arene p coordination and oxidative addition of a CΓ€X bond. Whereas oxidative addition of the C