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Coordination of 2,2‘-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes: An Experimental Investigation of Spin Coupling in Lanthanide Complexes

✍ Scribed by Schultz, Madeleine; Boncella, James M.; Berg, David J.; Tilley, T. Don; Andersen, Richard A.


Book ID
120185580
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
185 KB
Volume
21
Category
Article
ISSN
0276-7333

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The coordination chemistry of Ln(hfpd) 3 (hfpd=1,1,1,5,5,5-hexafluoropentane-2,4-dionate) with phen and bpy depends on the size of the Ln 3 + ion and on the used solvent. The complexes [Er(hfpd) 3 (phen)] ( 7) and [Er(hfpd) 3 (bpy)] ( 14) were obtained from the synthesis of Er(CF 3 SO 3 ) 3 with Hhf