Coordination Geometries of Metal Ions in Metallophthalocyaninato Complexes
β Scribed by R. Kubiak; J. Janczak
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 195 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0232-1300
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Sets of metal tetrapyrrole complexes are presented in which unusual geometries and/or stoichiometries occur as compared with the usual distorted octahedral structures and molar 1:1 ratio of metal and tetrapyrrole ligand normally found in metal complexes of porphyrins, phthalocyanines or other tetrap
The geometry optimization using natural internal coordinates was applied for transition metal complexes. The original definitions were extended here for the skeletal degrees of freedom which are related to the translational and rotational displacements of the n -bonded ligands. We suggest definition