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Coordination compounds of ambidentate 1-(H)alkyl-2-(2-pyridyl)benzimidazoles. Synthesis and crystal structure

✍ Scribed by A. S. Burlov; A. S. Antsyshkina; G. G. Sadkov; V. V. Chesnokov; Yu. V. Koshchienko; D. A. Garnovskii; I. S. Vasil’chenko; A. I. Uraev; G. S. Borodkin; V. S. Sergienko; A. D. Garnovskii


Book ID
111458557
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
283 KB
Volume
36
Category
Article
ISSN
1070-3284

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✍ Zhiyong Wang; Scott R. Wilson; Bruce M. Foxman; Wenbin Lin 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 239 KB

We have observed an unusual example of cobalt-mediated cyclization of 4-pyridinecarboxaldehyde and 2-nitroaniline to afford 2-(4-pyridyl)benzimidazole under hydro(solvo)thermal conditions. Reaction of Co(NO 3 ) 2 ⅐6H 2 O with 4-pyridinecarboxaldehyde and 2-nitroaniline in ethanol at 120°C gave a cob