Coordination chemistry of new sulfur containing ligands—XVIII: Metal complexes of ferrocenedithiocarboxylate
✍ Scribed by Robert D. Bereman; David P. Nalewajek
- Book ID
- 115976709
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 319 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-1902
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## Abstract The title compounds were prepared starting from the dihydropyrrolones **4**–**6**. Nucleophilic displacement and ring closure yielded the 1__H__‐pyrrolo[3,2‐__c__]isothiazol‐5(4__H__)‐ones **8** and **10**. The fused systems formed salts with strong acids and electrophiles (**15, 16**),
The pentadentate ligand N-(2-pyridylmethyl)-3-(bis(2-pyridylmethyl)amine)-propanamide (LH) and transition metal complexes hereof were synthesised. The negative charge of the deprotonated ligand was meant to stabilise metal ions in high oxidation states thus facilitating aerobic oxidation of the meta